To obtain Zygarde on Pokémon Quetzal (v0.8.2) you need to follow a series of specific steps. First, you must choose the protagonist from Kalos, have already captured both Xerneas and Yveltal, and build a team made up entirely of sixth-generation Pokémon. Once these requirements are met, Zygarde will be waiting for you at the end of the Z Crystal Cave located in the Battle Frontier.
To obtain Zygarde in its 10% Forme, place it in the Day Care along with a Ditto. To trigger its 100% Forme, it must happen during battle—once Zygarde's HP drops below half, its final form will automatically activate.
You can see how to get it in this video.
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